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Plastic Ice (The Fourth Form of Water)
 
Why in news?
 
Plastic Ice (Plastic Ice VII) is a newly confirmed, fourth form of water ice distinct from ordinary ice, liquid, and vapor. It occurs under extreme pressure and temperature conditions.
 


 
 
Key Characteristics:
  • Molecular Behavior: While it maintains a rigid crystalline (cubic) structure like a solid, the water molecules inside can rotate freely within this lattice, a feature similar to molecules in a liquid.
  • This molecular rotation inside a solid lattice is why it's called "plastic" ice—"plastic" refers to its ability to deform under pressure while retaining solidity, showing plasticity unlike conventional ice.
  • The structure allows it to behave as a hybrid between solid and liquid phases, a unique state unseen in normal ice forms.
 
Discovery:
  • First predicted theoretically in 2008, Plastic Ice VII was confirmed experimentally around 2025 by an international team led by physicist Livia Bove at Sorbonne University, France.
  • Scientists used quasi-elastic neutron scattering (QENS) combined with diamond-anvil cells to create and study tiny samples under extreme conditions, directly observing the rotational motion of molecules at the atomic scale while the lattice remained intact.
 
Applications & Significance:
  • Planetary Science: Explains water’s behavior inside icy moons (Ganymede, Callisto, Titan) and exoplanets.
  • Extreme Environment Research: Helps in understanding high-pressure physics and material science.
  • Space Exploration: Improves knowledge of ice phases in extreme planetary conditions, aiding in future astrobiology studies.
  • Hydrogen Storage & Energy Research: May have potential technological applications in material sciences.
 
Summary Table of Major Properties
Property Plastic Ice VII Ordinary Ice
Molecular arrangement Rigid cubic crystalline lattice Hexagonal or other crystal forms
Molecular motion Molecules rotate freely within lattice Fixed, no free rotation
Formation conditions Pressure >3 GPa, Temperature >450 K Near atmospheric pressure, below 0°C
Physical behavior Solid with plasticity (deformable) Brittle solid
Planetary occurrence Interiors of icy moons and exoplanets Earth's surface, common ice
Plastic Ice VII adds a fundamental new phase to H2O, expanding our comprehension of water's versatility in nature, especially beyond Earth

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